The Collector

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You may be looking for either the DWM comic story, the DWA comic story of the same name, or the species of the same name.

The Collector was a Usurian who, aided by his human assistant Hade, oversaw operations in Megropolis One on Pluto. The Usurians' Company had, by this time, made Pluto into a world inhabited by humans who lived in cities lit by artificial suns. The Collector, who in his native form resembled kelp, maintained a humanoid form on Pluto. When the Fourth Doctor reprogrammed the Company computer to apply a 2% growth tax, indexed, the loss of profits so upset the Collector that he reverted to his native form and was imprisoned with a champagne cork. (DW: The Sun Makers)