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The War Chief was a renegade Time Lord who assisted a group of aliens known as the War Lords.
The War Lords had been kidnapping soldiers from various wars in Earth's history to play war games on an unknown planet. The War Chief provided the War Lords with basic TARDIS-like travel machines, which they used to kidnap the human soldiers and travel between era-specific zones they had created.
When the War Chief and the Doctor came face to face, they recognised each other. The War Chief wanted the Doctor's help to double-cross the War Lords and seize power for himself. The Doctor immediately refused, and instead reluctantly summoned the Time Lords for help. The War Lords found out the War Chief's plans to betray them, and executed him. (DW: The War Games)