The Seventh Doctor sustained three gunshot wounds at the hands of a gang in San Francisco on 30 December 1999; one bullet went straight through his shoulder, inflicting no damage, while the other two were caught in his left leg before being removed at Walker General Hospital. (TV: Doctor Who)
Immediately following the Year That Never Was, Lucy Saxon inflicted a gunshot wound against the Saxon Master. Though the Tenth Doctor noted that the Master, as a Time Lord, could easily survive "one little bullet" by regenerating, the Master purposefully chose not to and so died. (TV: Last of the Time Lords)