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Emerald was a shade of green called after a certain gemstone.
Ace wore an emerald t-shirt under a black cardigan when she and the Seventh Doctor worked with UNIT to stop Morgana and the Destroyer. (TV: Battlefield)
Amy Pond wore an emerald t-shirt under her navy blazer. (TV: The Lodger)
Bill Potts wore an emerald velvet coat during a visit to the 1814 frost fair. (TV: Thin Ice)
The Eighth Doctor wore a cravat of emerald dupioni when he, Charley Pollard, and C'rizz confront the Kro'ka. (AUDIO: Caerdroia)
The Third Doctor wore a blazer of emerald velvet when he and Sarah Jane Smith helped to save Peladon from Ice Lord Commander Azaxyr and Eckersley. (TV: The Monster of Peladon)
Bliss wore an emerald jumper. (AUDIO: The Famished Lands)
The sixth incarnation of the Corsair wore emerald breeches. (COMIC: Old Friends)
The Reborn Master wore an emerald cravat when posing as 'the other Doctor'. (AUDIO: Dominion)