Cyanide

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The Doctor ejects cyanide in gas-like form. (DW: The Unicorn and the Wasp)

Cyanide was a white powder. It was poisonous to many species, though not to Birastrop (DW: The Brain of Morbius) or to Gallifreyans. (DW: The Unicorn and the Wasp)

References

Cyanide