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Brocade was a fabric and design with floral symbols invented on ancient China.
The Fourth Doctor wore an indigo brocade waistcoat with a fob watch when he met Magnus Greel in London during 1892. (TV: The Talons of Weng-Chiang)
The Seventh Doctor wore a single-breasted waistcoat of scarlet brocade up to his death. (TV: Doctor Who)
The Eighth Doctor wore some double breasted waistcoats of paisley-brocade with a gold fob watch; one in silver grey, (TV: Doctor Who) one in violet purple, (COMIC: Dreadnought) one in cream, (COMIC: Ophidius) one in ochre yellow, (AUDIO: The Stones of Venice) one in bracken green, (AUDIO: Caerdroia) and one in burnt orange. (AUDIO: The Devouring), Soon, he wore single-breasted waistcoats of paisley-brocade done in wine purple, (AUDIO: He Kills Me, He Kills Me Not,) plain vermillion, (AUDIO: Meanwhile, Elsewhere-Previously, Next Time) or bronze brown. (TV: The Night of the Doctor) His war successor wore the bronze one for some time. (TV: The Night of the Doctor; AUDIO: Light the Flame; WC: Doctors Assemble)
The Twelfth Doctor wore a sapphire blue brocade waistcoat during a visit to the 1814 frost fair. (TV: Thin Ice)
Jackson Lake wore a double-breasted waistcoat of scarlet brocade when he and Rosita worked with the Tenth Doctor to stop Cybermen from Pete's World during the 1851 Incident. (TV: The Next Doctor)
The Ninth Doctor wore a burgundy brocade cravat on 1912 Southampton. (TV: Rose)
In his Sixth Doctor form, the Curator wore a single-breasted waistcoat of amber and bronze brocade with a fob watch. (AUDIO: The Artist at the End of Time)
Rose Noble wore a crimson and peach brocade blouse during a dinner party. (TV: The Giggle)
Charles Dickens wore a single breasted waistcoat of ebony and gold brocade when he met the Ninth Doctor, Rose Tyler, Gwyneth, and the Gelth in Cardiff during 1869. (TV: The Unquiet Dead)
Gordon Jago and George Litefoot wore double-breasted waistcoats of brocade. (TV: The Talons of Weng-Chiang)
When poising as Professor Yana, the War Master wore a single breast waistcoat of wine purple brocade up to his death. His successor, the Saxon Master, wore it for some time. (TV: Utopia)
Rhys Williams wore a crimson and gold brocade waistcoat when he married Gwen Cooper. (TV: Something Borrowed)
Wrack. the leader of the Eternals on the Buccaneer, wears a bronze brocade vest. (TV: Enlightenment)
The Valeyard wore a copy of the Eighth Doctor's single-breasted waistcoat of bronze paisley-brocade. (AUDIO: The War Valeyard)