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A frock coat was a formal coat characterised by a knee-length skirt cut all around the base just above the knee, popular during the Victorian and Edwardian periods.
Worn by the Doctor
The First Doctor wore an Edwardian frock coat. (COMIC: Moon Landing, PROSE: Sanctuary)
The Second Doctor wore a black frock coat. (TV: The Power of the Daleks-The War Games, The Three Doctors, The Five Doctors, The Two Doctors) His successor, the Third Doctor, wore it briefly. (TV: Spearhead from Space)
The Fourth Doctor wore frock coats; one of mahogany brown velvet (TV: Pyramids of Mars, The Masque of Mandragora - The Deadly Assassin) one of grey tweed (TV: The Android Invasion et al) one of chocolate brown velvet, (TV: The Face of Evil et al) and one of light brown Harris tweed. (TV: The Power of Kroll et al)
The Fifth Doctor wore a beige frock coat with a scarlet trim. (TV: Castrovalva-Warriors of the Deep)
The Sixth Doctor initially wore a patchwork frock coat with several different colours and fabrics, (TV: The Twin Dilemma onwards) which he replaced with a similar coat in different shades of azure blue for a period (AUDIO: Real Time onwards) before returning to the original up to his death. (AUDIO: The Brink of Death; TV: Time and the Rani)
The Seventh Doctor spent his first hours in the Sixth Doctor's patchwork frock coat. He tried on a Napoleonic frock coat in navy and ivory with gold epaulettes and a crimson trim. He also tried a copy of the Fifth Doctor's beige frock coat with a scarlet trim for a silver grey safari jacket. (TV: Time and the Rani)
The Eighth Doctor wore many double-breasted frock coats of velvet done in forest green, (TV: Doctor Who) navy blue, (COMIC: Dreadnought), olive green, (COMIC: Ophidius), or dark brown. (PROSE: The Year of Intelligent Tigers)
On the Titanic launching of 1912, the Ninth Doctor wore an ebony black moleskin frock coat. (TV: Rose)
During his retirement to the Victorian era, the Eleventh Doctor wore a single-breasted frock coat of wine purple moleskin with black lamb fur lining. (TV: The Great Detective, The Snowmen) When travelling with Clara Oswald, he wore a frock coat of eggplant purple cashmere; (TV: The Bells of Saint John, etc) most notably when helping to foil the 1562/2013 Zygon Invasion of Earth and revisting the Fall of Gallifrey on the final day of the Last Great Time War, (TV: The Day of the Doctor) and before and after the Siege of Trenzalore. (TV: The Time of the Doctor)
The Twelfth Doctor wore the Eleventh Doctor's cashmere frock coat during his first hours. (TV: The Time of the Doctor, Deep Breath) He occasionally wore a single-breasted frock coat of raven black velvet with cornflower blue lining, (TV: The Pilot) or ebony black linen. (TV: World Enough and Time|The Doctor Falls, Twice Upon A Time)
The Fugitive Doctor wore a navy tweed frock coat. (TV: Fugitive of the Judoon, The Timeless Children, Once, Upon Time)
The Curator, taking the form of an older Sixth Doctor, wore frock coats; one of violet moleskin, (AUDIO: Crossed Lines) and one of burgundy and peach pinstripe. (AUDIO: The Artist at the End of Time)
Worn by Companions
Romana wore frock coats on rose pink, (TV: Destiny of the Daleks) scarlet, (TV: The Horns of Nimon) or beige. (TV: State of Decay)
Graham O'Brien wore a grey tweed frockcoat during a trip to New York during 1903. (TV: Nikola Tesla's Night of Terror). He and Ryan Sinclair also wore black frock coats when they met Mary Shelley, Lord George Gordon Byron, John Polidori, Claire Clairmont, and Ashad on 1816. (TV: The Haunting of Villa Diodati)
Won by the Master
Many versions of the Master wore frock coats.
The War Master wore a battleship grey tweed frock coat. (AUDIO: Masterful)
The Saxon Master wore a black, asymmetrical frock coat, (TV: World Enough and Time) right up to his death. (TV: The Doctor Falls)
The Spy Master wore a charcoal grey frock coat when confronting the Thirteenth Doctor on London during 1834. (TV: Spyfall)
Worn by others
The Toymaker wore a frock coat done in scarlet and ivory with gold trims as part of his drum major outfit when he plays the Spice Girls song Spice Up Your Life while messing with UNIT in London during 2023. (TV: The Giggle)
Charles Dickens and Gabriel Sneed wore black frock coats when they met the Ninth Doctor, Rose Tyler, and the Gelth on 1869. (TV: The Unquiet Dead)
Mr Scoones, Mr Cole, Mr Fetch and Mr Milligan wore black frock coats up to when they died during the 1851 Incident. (TV: The Next Doctor)
Webley wore a double breasted frock coat of bottle green tweed with a scarlet overcheck up to his death during the Battle of Hedgewick's World of Wonders. (TV: Nightmare in Silver)
Doctor Ogron wore a copy of the Eighth Doctor's forest green frock coat. (AUDIO: Planet of the Ogrons)
Rhys Williams wore a black frock coat when he married Gwen Cooper. (TV: Something Borrowed)
Edward Waterfield and Theodore Maxtible wore frock coats; Edward's navy and Theodore's charcoal. Both did this during the Dalek Empire's Operation Human Factor. (TV: The Evil of the Daleks)